Tris(polymethoxyphenyl)bismuth derivatives: Synthesis and reactivity |
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| Authors: | Jean-Pierre Finet |
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| Affiliation: | a Laboratoire “Chimie, Biologie et Radicaux Libres” UMR 6517 CNRS-Universités d’Aix-Marseille 1, 2 et 3, Faculté des Sciences Saint-Jérôme, Case 521, 13397 Marseille Cedex 20, France
b Department of Chemistry, Nizhnii Novgorod N. I. Lobachevsky State University, 23 Gagarin Avenue, 603950 Nizhnii Novgorod, Russia |
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| Abstract: | Tris-(polymethoxyphenyl)bismuth diacetate and dichloride derivatives react with C-nucleophiles in basic medium, as well as with N- and O-nucleophiles under copper catalysis to give good to high yields of the corresponding C-, N- and O-arylation products. |
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| Keywords: | Organobismuth derivatives Reductive coupling reactions C-, O- and N-arylation reactions |
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