|
|||||
|
|
Synthesis of platinum-iodo-alkyl/aryl complexes in ligand-exchange reactions: Determination of the structure of Pt{(S,S)-bdpp}(X)I complexes (X = Me, I) by X-ray crystallography |
|
| Authors: | László Jánosi Piero Macchi |
| Institution: | a University of Pécs, Department of Inorganic Chemistry, H-7624 Pécs, Ifjúság, P. O. Box 266, Hungary b Research Group for Chemical Sensors of the Hungarian Academy of Sciences, H-7624 Pécs, P.O. Box 266, Hungary c Dipartimento di Chimica Strutturale e Stereochimica Inorganica dell’Università di Milano, Via G. Venezian 21, 20133 Milano, Italy |
| Abstract: | Pt{(S,S)-bdpp}(R)I (bdpp = 2,4-bis(diphenylphosphino)pentane; R = Me, Ph, Bz, 2-Tioph) complexes were formed in alkyl/aryl ligand - iodide ligand-exchange reactions by reacting the corresponding Pt{(S,S)-bdpp}R2 complexes with methyl iodide. The Pt{(S,S)-bdpp}(Me)I complex was isolated and fully characterised. The influence of the X ligand on the platinum-bdpp chelate conformation was investigated in Pt{(S,S)-bdpp}(X)I (X = I, SnCl3, Me) complex series by means of X-ray crystallography. |
| Keywords: | Platinum Iodo-complex X-ray crystallography Chelate |
| 本文献已被 ScienceDirect 等数据库收录！ | |