1,1′-Bis(phosphoranylidenamino)ferrocene palladium(II) complexes: An unusual case of dative Fe → Pd bonding |
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| Authors: | Costa Metallinos Deanna Tremblay Nicholas J Taylor |
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| Institution: | a Department of Chemistry, Brock University, St. Catharines, Ont., Canada L2S 3A1
b Department of Chemistry, University of Waterloo, Waterloo, Ont., Canada N2L 3G1 |
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| Abstract: | Subtle differences in the electron-richness of nitrogen atoms in 1,1′-bis(phosphoranylidenamino)ferrocenes can change the coordination geometry of their palladium(II) complexes from cis to trans. Trans complexation results in concomitant formation of a relatively short dative Fe-Pd bond of 2.67 Å. |
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| Keywords: | Ferrocene Iminophosphorane Palladium Complex Dative bond |
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