Derivatives of 1,1′-bis(diphenylphosphino)ferrocene (dppf): Electrochemistry, complexation and the X-ray structures of 1,1′-bis(diphenylphosphino)osmocene (dppo) and [PdCl2(dppo)] |
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| Authors: | Sarah L Martinak Sarah J Kolb William R McNamara James A Golen Chip Nataro |
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| Institution: | a Department of Chemistry, Lafayette College, Easton, PA 18042, United States
b Department of Chemistry and Biochemistry, University of California - San Diego, La Jolla, CA 92093, United States |
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| Abstract: | The oxidative electrochemistry of 1,1′-bis(diphenylphosphino)osmocene (dppo) and 1,1′-bis(diphenylarsino)ferrocene (dpaf) was studied in dichloromethane with tetrabutylammonium hexafluorophosphate as the supporting electrolyte. The MCl2(P∩P)] (M = Pd or Pt; P∩P = dppo or 1,1′-bis(diphenylphosphinoindenyl)iron) complexes were prepared, studied electrochemically and the X-ray structures of dppo and PdCl2(dppo)] were determined. |
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| Keywords: | Electrochemistry Cyclic voltammetry Crystal structures 1 1&prime -Bis(diphenylphosphino)osmocene 1 1&prime -Bis(diphenylarsino)ferrocene 1 1&prime -Bis(diphenylphosphinoindenyl)iron |
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