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Enantioselective addition of diethylzinc to aldehydes in the presence of chiral hydrazone and imine ligands |
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| Authors: | Takashi Mino Atsushi Suzuki Shusaku Narita Masami Sakamoto |
| Affiliation: | a Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba 263-8522, Japan b Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0394, Japan |
| Abstract: | Optically active hydrazone and imine were found to act as effective ligands for enantioselective addition of diethylzinc to aldehydes. This reaction provided optically active secondary alcohols with ee up to 71%. |
| Keywords: | Hydrazone Imine Enantioselective addition Diethylzinc Secondary alcohol |
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