Gallium and indium dithiocarboxylates: Synthesis, spectroscopic characterization and structure of [MeGa(S2Ctol)2] |
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| Authors: | Shamik Ghoshal Dimple P Dutta Munirathinam Nethaji |
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| Institution: | a Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085, India
b Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India |
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| Abstract: | Several gallium and indium dithiocarboxylate complexes of the type MenM(S2CR)3−n] (M = Ga, In; n = 0, 1, 2; R = phenyl (Ph), p-tolyl (tol), mesityl (Mes)) have been synthesized. These complexes were characterized by elemental analysis, IR, UV-vis and NMR (1H,13C{1H}) spectroscopy. Structure of MeGa(S2Ctol)2] was established by X-ray crystallography. The gallium atom adopts a distorted five coordinate geometry which is intermediate between trigonal bipyramidal and square pyramidal configurations. The complex Me2InS2Ctol] underwent a two-step thermal decomposition leading to the formation of tetragonal β-In2S3. |
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| Keywords: | Gallium Indium Dithiocarboxylates NMR X-ray In2S3 |
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