Palladium-catalyzed three-component coupling reaction of organic halides, norbornadiene and terminal alkynes |
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Authors: | Yu-Cheng Chang |
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Institution: | Department of Applied Chemistry, Chia Nan University of Pharmacy and Science, Tainan 717, Taiwan, ROC |
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Abstract: | A three-component coupling reaction of organic halides, including aryl halides, methyl iodine, alkenyl iodine and bromoalkynes, with norbornadiene and terminal alkynes catalyzed by a palladium complex and a phase transfer agent in the presence of aqueous NaOH gave 5,6-disubstituted norbornene derivatives in good yields. |
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Keywords: | Multi-component reaction Norbornadiene Bromoalkyne Terminal alkyne Dialkynyl norbornene |
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