Electrochemical alkyl transfer reaction from trialkylboranes to polyhalo compounds |
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| Authors: | Sylvie Condon,Chunhai Zou,Jean-Yves Né dé lec |
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| Affiliation: | Laboratoire d’Electrochimie Catalyse et Synthèse Organique, Université Paris XII, CNRS, UMR 7582, 2 rue Henri Dunant 94320 Thiais, France |
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| Abstract: | Reduction of decyl dichloro- and trichloroacetate, under mild electrolysis conditions by using the sacrificial anode process, affords α-chlorocarbanions which readily react with trialkylboranes to give alkylated products in a one step reaction. |
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| Keywords: | Electrochemistry Alkylation Trialkylborane Polyhalo compound |
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