SnCl2 mediated efficient N,N-dialkylation of azides to tertiary-amine via potential stannaimine intermediate |
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| Authors: | Ujjal Kanti Roy |
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| Institution: | Organometallics and Catalysis Laboratory, Chemistry Department, Indian Institute of Technology, Kharagpur 721302, India |
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| Abstract: | A base free one-pot conversion of azides to N,N-dialkylamine is described. A two-step reaction pathway has been postulated invoking the intermediacy of stannaimine. This new carbon-nitrogen bond formation strategy adds to the repertoire of tin(II) chemistry. |
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| Keywords: | Stannaimine Sn-N Tin(II) Tin(IV) Azides Amine |
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