Preparation and structural characterization of tetracoordinated tungsten(II) diazadiene complexes |
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| Authors: | Thouraya Turki Faouzi Bouachir |
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| Affiliation: | a Laboratoire de Chimie de Coordination, Faculté des Sciences de Monastir, 5019 Monastir, Tunisia
b Laboratoire de Chimie du Solide, Faculté des Sciences de Monastir, 5019 Monastir, Tunisia |
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| Abstract: | Reduction in situ of WCl4(MeCN)2 with zinc in the presence of diazadiene ligands 1b-f is reported and produces a series of diamagnetic complexes (DAD)WCl22b-f. All complexes were characterized by 1H, 13C NMR and IR spectroscopic data. The crystal structures of complexes 2b and 2e were solved by X-ray diffraction methods. |
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| Keywords: | Tungsten Chemical reduction Tungsten(II) diazadiene complexes α-Diimine X-ray crystallographic determination |
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