Hexapalladium cluster: Unique cluster construction reaction of cyclic Pd3(CNC6H3Me2-2,6)6 and linear [Pd3(CNC6H3Me2-2,6)8] |
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| Authors: | Masato Ohashi |
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| Institution: | Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan |
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| Abstract: | Reaction of a triangle Pd(0) complex, Pd3(CNXyl)6 (1; Xyl = 2,6-C6H3Me2), with a dicationic linear trinuclear complex Pd3(CNXyl)8]PF6]2 (3) afforded a dicationic hexapalladium complex Pd6(CNXyl)12]PF6]2 (4), while the reaction of 1 with a dicationic dinuclear complex Pd2(CNXyl)6]PF6]2 (2) resulted in the formation of 3. The molecular structure of the complex 4 was determined by X-ray crystallography and spectroscopic analysis. |
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| Keywords: | Palladium Isocyanide Homoleptic complex Hexanuclear cluster |
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