Reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid and synthesis of ammine(nitrato)nitrosoruthenium complexes |
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| Authors: | E. V. Kabin V. A. Emel’yanov V. A. Vorob’yev N. I. Alferova S. V. Tkachev I. A. Baidina |
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| Affiliation: | 1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent??eva 3, Novosibirsk, 630090, Russia
2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia
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| Abstract: | The reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid has been studied. Reaction products have been identified by IR spectroscopy, NMR, mass spectrometry, powder and single-crystal X-ray diffraction, and chemical analysis. Synthesis methods have been developed for amminenitrosoruthenium complexes containing outer-sphere and coordinated nitrate ions: trans-[RuNO(NH3)4(H2O)](NO3)3 (I), trans-[RuNO(NH3)4(NO3)](NO3)2 (II), and fac-[RuNO(NH3)2(NO3)3] (III). Complex II has two polymorphs: monoclinic and tetragonal. The latter has been studied by X-ray crystallography. |
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