Molecular-glue-triggered DNA assembly to form a robust and photoresponsive nano-network |
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Authors: | Wang Chunyan Pu Fang Lin Youhui Ren Jinsong Dohn Chikara Nakatani Kazuhiko Qu Xiaogang |
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Affiliation: | State Key laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022 PR China. |
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Abstract: | A robust and photoresponsive DNA network has been designed and constructed from branched DNA and molecular glue. The molecular glue is photoswitchable and can specifically bind to G-G mismatched double-stranded DNA. The assembly process can be reversibly controlled by manipulating the wavelength of light. The approach is flexible, allowing tuning of the size, morphology as well as the cavity of the network by variation of the molar ratio and the isotropic/anisotropic character of the branched building blocks. The assembled architectures are versatile and heat tolerant. These properties should allow the use of the network in further applications. |
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Keywords: | DNA structures molecular glue nanostructures photochemistry supramolecular chemistry |
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