Multiple-ionization satellites in the L
2, 3 Auger spectra of argon-like molecules |
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Authors: | S A Novikov Ya S Akop’yan A G Kochur M E Vasil’eva |
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Institution: | (1) Rostov State University of Transport Communications, Rostov-on-Don, 344038, Russia |
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Abstract: | L 2, 3 Auger spectra of all argon-like molecules (HCl, H2S, PH3, SiH4) have been calculated with inclusion of the multiple ionization satellites. The Auger transition probabilities were calculated with inclusion of the ligand electron density, multiplet splitting, final-state configuration interaction, and spin-orbit splitting of the initial 2p level. The theoretical integrated intensities of the shake-off and shake-up satellites (“with a spectator”) in the L 2, 3 Auger spectra of argon-like molecules make up 8.2–10.4% of the total Auger spectrum intensity. |
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