Condensed tetrazolo-1,3,5-triazines. 4. Synthesis of salts of 5-aminotetrazolo[1,5-a]-1,3,5-triazin-7-one |
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| Authors: | V V Bakharev A A Ghidaspov D B Krivolapov E V Mironova I A Litvinov |
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| Institution: | (1) Samara State Technical University, Samara, 443100, Russia;(2) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Science Center of the Russian Academy of Sciences, Kazan, 420088, Tatarstan Republic |
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| Abstract: | 2-Amino-4-azido-1,3,5-triazin-6(1H)-ones were synthesized by successive substitution of the trinitromethyl groups in 2-amino-4,6-bis(trinitromethyl)-1,3,5-triazines
under the influence of azide and nitrite ions. Interaction of 2-amino-4-azido-1,3,5-triazin-6(1H)-ones with bases led to the
azido-tetrazole tautomeric conversion give salts of 5-aminotetrazolo1,5-a]-1,3,5-triazin-7-one.
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1211–1219, August, 2006. |
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| Keywords: | 2-amino-4-azido-1 3 5-triazin-6(1H)-one 2-amino-4 6-bis(trinitromethyl)-1 3 5-triazines salts of 5-aminotetrazolo[1 5-a]-1 3 5-triazin-7-one azido-tetrazole tautomeric conversion |
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