A phenyl-substituted germole dianion and its reaction with hafnocene dichloride |
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| Institution: | Institute of Chemistry, Carl von Ossietzky University Oldenburg, 26129 Oldenburg, Germany |
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| Abstract: | The reaction of phenyl-substituted dipotassium germacyclo-pentadienediide with one equivalent of hafnocene dichloride at low temperature provides a bicyclic germylene. With two equivalents of hafnocene dichloride, a dinuclear hafnium complex with a mmm-coordinating germolyl dianion ligand is formed. |
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| Keywords: | Germanium Germoles Organogermanium compounds Hafnium complexes Anions Aromaticity |
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