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A phenyl-substituted germole dianion and its reaction with hafnocene dichloride
Institution:Institute of Chemistry, Carl von Ossietzky University Oldenburg, 26129 Oldenburg, Germany
Abstract:The reaction of phenyl-substituted dipotassium germacyclo-pentadienediide with one equivalent of hafnocene dichloride at low temperature provides a bicyclic germylene. With two equivalents of hafnocene dichloride, a dinuclear hafnium complex with a mmm-coordinating germolyl dianion ligand is formed.
Keywords:Germanium  Germoles  Organogermanium compounds  Hafnium complexes  Anions  Aromaticity
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