Preparation and crystal structure of C84(11)Cl20,22, chloro derivatives of a C84 minor isomer |
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| Institution: | 1. Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, 230026 Hefei, China;2. Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation |
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| Abstract: | Chlorofullerenes C84(11)Cl20 and C84(11)Cl22 were prepared by chlorination of C2–C84(11) with VCl4 at 340–360 °C. An X-ray crystallographic study with the use of synchrotron radiation revealed the chlorination patterns featuring only para additions in C6Cl2 hexagons. |
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| Keywords: | higher fullerenes chlorination IPR isomers structure elucidation |
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