Energetic heterocyclic N-oxides: synthesis and performance |
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Institution: | N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation |
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Abstract: | Novel synthetic strategies toward construction and functionalization of nitrogen-rich energetic compounds bearing at least one heterocyclic N-oxide scaffold are briefly overviewed. The present focus review summarizes main recent advances (published in the period 2017–2022) in the chemistry of five- and six-membered heterocyclic N-oxides as well as their linear combinations and fused bi-, tri- and tetraheterocyclic frameworks which are of paramount importance for the development of next-generation energetic materials. Physicochemical properties along with detonation performance and mechanical sensitivities of the reported high-energy substances are discussed and their application potential is especially emphasized. |
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Keywords: | energetic materials nitrogen heterocycles fused heterocycles detonation performance synthetic methodologies |
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