Synthesis and structure of (O → Si)-chelate fluorosilane,a novel complex of pentacoordinate silicon with N-acetylvaline |
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| Institution: | 1. N. I. Pirogov Russian National Research Medical University, 117997 Moscow, Russian Federation;2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991 Moscow, Russian Federation;3. D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation;4. The Open University, Walton Hall, Milton Keynes MK7 6AA, UK |
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| Abstract: | A novel organosilicon complex of N-acetylvaline was synthesized by the reaction of the relative disiloxane derivative with BF3 etherate. According to X-ray and NMR data, the silicon atom of the final product is pentacoordinated in both the solid state and solution. The coordination state of silicon was correctly predicted by quantum-chemical calculations. |
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