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Effect of pH on the reaction outcome between tetraacetyl hexaazaisowurtzitane and aldehydes
Affiliation:Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Sciences, 659322 Biysk, Russian Federation
Abstract:2,6,8,12-Tetraacetyl-2,4,6,8,10,12-hexaazaisowurtzitane was subjected to N-aminomethylation under various conditions, which afforded new derivatives of aminal nature. The highest yields were achieved when the reactions were carried out in a weak-alkali medium.
Keywords:hexaazaisowurtzitanes  formaldehyde  aldehydes  acetals  aminals  cage compounds
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