Synthesis and characterization of amantadinium iodoacetatobismuthate,a hybrid compound with mixed iodide–carboxylate anions |
| |
| Institution: | 1. Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation;2. Department of Materials Sciences, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation;3. Department of Chemistry, University at Albany, Albany, NY 12222, USA |
| |
| Abstract: | The amantadinium iodoacetatobismuthate(III) C10H15NH3·(CH3)2CO]2BiI3.67(CH3COO)1.33] is a new hybrid halometallate with iodide ions partially replaced by oxygen-containing acetates to form stronger interaction between the anionic and cationic substructures. The title compound as well-shaped orange-red crystals was synthesized by a facile reaction in acetone solution in the presence of glacial acetic acid. The crystal structure of the compound consists of the infinite anionic chains BiI3.67(CH3COO)1.33]2– and the countercations C10H15NH3·(CH3)2CO]+; according to the optical absorption data, the test compound is a semiconductor with a band gap of 2.06 eV. |
| |
| Keywords: | Amantadine Iodide Bismuth Acetate Perovskite photovoltaics |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
