An effective Pd-catalyzed hydroxycarbonylation of olefins with CO and HCOOH |
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| Institution: | N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation |
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| Abstract: | A new protocol for Pd-catalyzed regioselective hydroxy-carbonylation of olefins with formic acid under low pressure of carbon monoxide has been developed. The same catalytic system provides good selectivity to 2-phenylpropionic acid in carbonylation of styrene and to linear acids in carbonylation of terminal alkenes. The reaction is highly susceptible to catalyst precursor and solvent nature. |
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| Keywords: | hydroxycarbonylation palladium olefins carboxylic acids formic acid carbon monoxide |
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