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A comparison of homogeneous and heterogeneous copper catalyzed arylation of amines |
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| Affiliation: | 1. Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation;2. Volgograd State Technical University, 400005 Volgograd, Russian Federation;3. Instituto de Química, Universidade Estadual de Campinas (UNICAMP), 13084-971 Campinas, São Paulo, Brazil |
| Abstract: | Comparison of the homogeneous and heterogeneous copper-catalyzed arylation of model primary amines with (hetero)-aryl iodides in DMSO revealed a comparable efficiency of CuI and commercially available unsupported copper nanoparticles (25 nm size) in the presence of 2-isobutyryl-cyclohexanone or L-proline. |
| Keywords: | amination copper homogeneous catalysis heterogeneous catalysis nanoparticles iodoarenes |
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