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Crystal structure of copper bis(tenuazonate) monohydrate
Authors:A. Dippenaar  C. W. Holzapfel  J. C. A. Boeyens
Affiliation:(1) Present address: National Institute for Metallurgy, Randburg;(2) Present address: National Chemical Research Laboratory, P.O. Box 395, 0001 Pretoria, South Africa;(3) Department of Chemistry, Rand Afrikaans University, Johannesburg
Abstract:The crystal structure of copper bis(tenuazonate) monohydrate has been determined by X-ray diffraction from 968 counter-measured intensities. The thin flat crystals are monoclinic,P21, witha = 13.77(1),b = 15.51(1),c = 11.14(1) Å, beta = 109.5(2) °, and two formula units, C20H26CuN2O6·H2O, per asymmetric unit. The structure was refined by full-matrix least squares toR = 0.056. Because of the dimerization one copper ion is four- and the other five-coordinate. The dimers are hydrogenbonded into sheets by water molecules.NIM Applied Structural Chemistry Research Group
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