Compounds of hypercoordinated gold(i) |
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| Authors: | T V Baukova V P Dyadchenko N A Oleinikova D A Lemenovskii L G Kuz'mina |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Conpounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(2) Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 117234 Moscow, Russian Federation;(3) N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117907 Moscow, Russian Federation |
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| Abstract: | A binuclear organic derivative of gold(i) with diphenylmethane CH2(C6H4)2(AuPPh3)2 has been prepared by the reaction of 2,2 -dilithiumdiphenylmethane with ClAuPPh3. X-ray analysis of this compound revealed a transoid conformation of the molecule with agostic bonds between the gold atoms and methylene hydrogens. The complex was characterized by IR,1H and31P NMR, and mass spectral data.For Report 1 seeRuss. Chem. Bull., 1994,43, 681.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1125–1130, June, 1994.This work was performed with partial financial support from the International Science Foundation (Project No. MDV 000). |
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| Keywords: | i)" target="_blank">hypercoordinated gold(i) organic derivatives agostic interactions synthesis diphenylmethane X-ray diffraction study |
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