Thiylation of Functionalized Electrophiles with Sulfur in Basic Reductive Systems |
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| Authors: | Deryagina E N Russavskaya N V Grabel'nykh V A |
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| Institution: | (1) Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, Russia |
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| Abstract: | Functionalized electrophiles, specifically acetyl chloride, benzoyl chloride, chloroacetylchloride, benzenesulfonyl chloride, and N,N,4-trichlorobenzenesulfonamide, were brought into reaction with sulfur in the systems hydrazine hydrate-NaOH and sodium sulfide-water-ethanol. The efficiencies of these systems were compared. The reaction of chloroacetyl chloride with sulfur in the system hydrazine hydrate-base afforded new types of polymeric compounds, poly(diacylhydrazine)polysulfides]. The reaction mechanisms were discussed. |
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