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Pillararene-based fluorescent sensors for the tracking of organic compounds
Affiliation:1. Hainan Provincial Key Laboratory of Fine Chemicals, Advanced Materials of Tropical Island Resources of Ministry of Education, College of Chemical Engineering and Technology, Hainan University, Haikou 570228, China;2. MediCity Research Laboratory, University of Turku, Tykistökatu 6, Turku 20520, Finland
Abstract:Fluorescent chemosensors based on pillararene complexes represent a new, promising branch in sensor technology. Because of CH⋅⋅⋅π interactions, aliphatic chains are well suited for the columnar cavities of pillararenes and bulky or sheet-like (sub)structures can be arranged on the portals. Thus, pillararenes form versatile receptors and an alteration of the fluorescence behavior upon complexation ensures the function of these chemosensors as the reporter. Although this field of research exists only since a few years, remarkable chemosensors were developed for substances as diverse as medical drugs, biochemicals, herbicides and explosives.
Keywords:Pillararene  Fluorescent chemosensor  Complex  Host-guest  Fluorescent cavity
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