Decarbonylative C-h coupling of azoles and aryl esters: unprecedented nickel catalysis and application to the synthesis of muscoride a |
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Authors: | Kazuma Amaike Kei Muto Junichiro Yamaguchi Kenichiro Itami |
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Affiliation: | Department of Chemistry, Graduate School of Science, Nagoya University , Nagoya 464-8602, Japan. |
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Abstract: | A nickel-catalyzed decarbonylative C-H biaryl coupling of azoles and aryl esters is described. The newly developed catalytic system does not require the use of expensive metal catalysts or silver- or copper-based stoichiometric oxidants. We have successfully applied this new C-H arylation reaction to a convergent formal synthesis of muscoride A. |
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