Quasi-reversible voltammetric response of electrodes coated with electroactive monolayer films |
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| Institution: | 1. Institute of Solid Mechanics, Technische Universität Dresden, 01062 Dresden, Germany;2. Dresden Center for Computational Materials Science (DCMS), Technische Universität Dresden, 01062 Dresden, Germany |
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| Abstract: | Quasi-reversible voltammetric response of the surface-confined redox species is treated, including both ion pairing and double-layer effects. The Smith–White model and the Butler–Volmer formulation are chosen as the electrode|solution interface model and the electrode kinetics, respectively. An algorithm to simulate the voltammogram is derived. |
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