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Enhanced photoresponse of poly(3-methylthiophene) supported on TiO2
Affiliation:1. Department of Materials Physics, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603, Japan;2. Nanostructures Research Laboratory, Japan Fine Ceramics Center, 2-4-1 Mutsuno, Atsuta, Nagoya 456-8587, Japan;3. PRESTO, Japan Science and Technology Agency (JST), 7, Gobancho, Chiyoda-ku, Tokyo 102-0076, Japan
Abstract:We have investigated the photoelectrochemical behavior of poly(3-methylthiophene) supported on nanostructured n-TiO2 in a solid-state photoelectrochemical device. As electrolyte we employed the elastomer poly(epichlorohydrin-co-ethylene oxide) filled with NaI/I2. Under polychromatic light irradiation (60 mW cm−2) the device exhibits an open circuit voltage, a short-circuit current and fill factor of 10 μA cm−2, 0.048 V and 0.29, respectively. The overall efficiency of the cell is 2.3×10−2%.
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