Adamantylazoles: X. Reactions of 1,2,4-Triazole-3-thione with 1-Adamantanol in Acid Solutions |
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| Authors: | A. D. Amandurdyeva V. V. Saraev I. N. Polyakova E. L. Golod |
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| Affiliation: | (1) St. Petersburg State Institute of Technology, Technical University, St. Petersburg, Russia;(2) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia |
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| Abstract: | 1,2,4-Triazole-3-thione reacts with 1-adamantanol in concentrated sulfuric acid to form 1-(1-adamantyl)-1,2,4-triazole-3-thione, which transforms into 1-(1-adamantyl)-3-(1-adamantyl)sulfanyl-1,2,4-triazole or is oxidized with atmospheric oxygen dissolved in sulfuric acid into 3,3′-disulfanediylbis[1-(1-adamantyl)- 1,2,4-triazole]. 3-(1-Adamantyl)sulfanyl-1,2,4-triazole was prepared by adamantylation of 1,2,4-triazole-3-thione in a mixture of phosphoric and acetic acid (weight ratio 4 : 1). |
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