Dinitrogen complexes of chromium(III) with chelating agents |
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| Authors: | Juan M. López-Alcalá M. C. Puerta F. González-Vílchez |
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| Affiliation: | (1) Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, Cádiz, España |
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| Abstract: | Summary Two new dinitrogen complexes of CrIII with EDTA and CDTA have been prepared from reaction of [Cr(Y-H)H2O] (Y = EDTA, CDTA) with sodium azide in aqueous solution. Both complexes exhibit characteristic bands at 2070 cm–1 in the i.r. spectra corresponding to  (N2). The 10 Dq and B parameters were calculated from the u.v. visible spectra. |
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