Oxidation of secondary alcohols byN-methylmorpholine-N-oxide (NMO) catalyzed by atrans-dioxo ruthenium(VI) complex or perruthenate complex: A kinetic study |
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| Authors: | K. J. Tony V. Mahadevan J. Rajaram C. S. Swamy |
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| Affiliation: | (1) Department of Chemistry, Indian Institute of Technology, 600 036 Madras, India |
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| Abstract: | Thetrans-dioxo ruthenium (VI) complex, [P(C6H5)3C6H5CH2]+[Ru(O)2OAcCl2] or tetrapropylammonium perruthenate catalyzes the oxidation of secondary alcohols to ketones byN-methylmorpholine-N-oxide (NMO). Kinetic studies showed the formation of a complex between catalyst and substrate (alcohol) as the first step in the mechanism. |
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| Keywords: | Secondary alcohols catalytic oxidation N-methylmorpholine-N-oxide |
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