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Correlations between gas permeation and free-volume hole properties probed by positron annihilation spectroscopy
Authors:Y. C. Jean  J.-P. Yuan  J. Liu  Q. Deng  Hsinjin Yang
Abstract:Free-volume hole sizes, fractions, and distributions in a series of polycarbonate-based polymers are measured by using positron annihilation lifetime (PAL) spectroscopy. Correlations between the obtained free-volume hole properties and gas diffusion coefficients are observed. © 1995 John Wiley & Sons, Inc.
Keywords:positron annihilation  positronium  free volume  hole  gas permeation
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