The reaction of direct phenylation by nucleogenic cations as a method of synthesis of unknown or complicated tritium labeled compounds |
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| Authors: | N. E. Shchepina V. V. Avrorin G. A. Badun S. B. Lewis V. M. Fedoseev S. E. Ukhanov |
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| Affiliation: | (1) Natural Sciences Institute, Perm State University, Perm, 614990, Russia;(2) St. Petersburg State University, St. Petersburg, 199034, Russia;(3) M. V. Lomonosov Moscow State University, Moscow, 119991, Russia;(4) James Madison University, Harrisonburg, VA, USA |
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| Abstract: | As a result of ion-molecular reactions of nucleogenic phenyl cations, generated by tritium β-decay in polytritiated benzene, with nucleophilic centers of investigated substrates the direct phenylation has been realized at first time and unknown tritium labeled aromatic derivatives of polyvalent fluorine together with the different N-phenyl substituted pyridinium compounds which are important syntones for biological and medical investigations have been synthesized. |
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