Synthesis of optically pure 1,2-diaryl- and 1,2-alkylaryl-1,2-amino sulfides |
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| Authors: | Arroyo Yolanda Meana Angela Rodríguez J Félix Santos Mercedes Sanz-Tejedor M Ascensión García Ruano José L |
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| Affiliation: | Departamento de Química Orgánica (ETSII), Universidad de Valladolid, Po. del Cauce s/n, 47011 Valladolid, Spain. |
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| Abstract: | [reaction: see text] The reactions of the lithium (S)-alpha-(methylthio)-2-(p-toluenesulfinyl)benzyl carbanion with (S)-N-p-tolylsulfinyl aldimines evolve in a completely stereoselective manner providing a one-step synthesis of enantiomerically pure anti-1,2-disubstituted 1,2-amino sulfide derivatives. |
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