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Hydrothermal synthesis of the fist two‐dimensional folded layer formed by a cyano‐bridged one‐dimensional chain joined by Cu(I)?Cu(I) bonding |
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| Authors: | Xiong‐Bin Chen Yi‐Zhi Li Xiao‐Zeng You |
| Abstract: | Two cyano‐bridged polymers, Cu3(CN)3(phen)]n ( 1 ) and Cu(CN)(phen)]n ( 2 ) (phen = 1,10‐phenphralonine), were synthesized by the hydrothermal reaction of Cu(NO3)2· 3H2O, K3Fe(CN)6] and phen and were characterized structurally by X‐ray, IR and ERSC methods. Compound 1 shows a two‐dimensional folded coordination network by Cu(I)? CN? Cu(I) and Cu(I)? Cu(I) interaction, while compound 2 exhibits an infinite helix chain by Cu(I)? CN linkages. Copyright © 2005 John Wiley & Sons, Ltd. |
| Keywords: | hydrothermal synthesis chain copper(I) cyano‐bridged |