The anion sequence in the phase transformation of mesostructures templated by non-ionic block copolymers |
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| Authors: | Tang Jiawei Yu Chengzhong Zhou Xufeng Yan Xiaoxia Zhao Dongyuan |
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| Affiliation: | Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, PR China. |
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| Abstract: | A p6m to Ia3d mesophase evolution is achieved by simply adjusting the acidity and/or anion species in the presence of block copolymers; the unusual anion sequence that affects the phase behavior of block copolymer templated mesostructured solids is revealed to be SO(4)(2-)(HSO(4)(-)) > NO(3)(-) > Br(-) > Cl(-). |
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