Study of the reactivity of organonickel sigma-complexes towards nitriles |
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| Authors: | Z N Gafurov I F Sakhapov V M Babaev A B Dobrynin V A Kurmaz K E Metlushka I Kh Rizvanov G R Shaikhutdinova O G Sinyashin D G Yakhvarov |
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| Institution: | 1.A. E. Arbuzov Institute of Organic and Physical Chemistry,Russian Academy of Sciences,Kazan,Russian Federation;2.A. M. Butlerov Institute of Chemistry,Kazan Federal University,Kazan,Russian Federation;3.Institute of Problems of Chemical Physics,Russian Academy of Sciences,Chernogolovka,Russian Federation |
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| Abstract: | The reactivity of organonickel sigma-complexes of type NiBr(Ar)(bpy)], where Ar = 2,6-dimethylphenyl (Xyl), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp), 2,4,6-tricyclohexylphenyl (Tchp), bpy = 2,2´-bipyridine, towards nitriles (acetonitrile, propionitrile, chloroacetonitrile, benzonitrile) has been investigated. This reaction leads to imines by formation of new carbon—carbon bond between aromatic fragment and nitrile group C≡N. |
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