Selective aqueous-phase hydrogenation of furfural to cyclopentanol over PdRu/C catalyst |
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| Authors: | R. M. Mironenko O. B. Belskaya A. V. Lavrenov V. A. Likholobov |
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| Affiliation: | 1.Institute of Hydrocarbons Processing,Siberian Branch of the Russian Academy of Sciences,Omsk,Russian Federation;2.Dostoevsky Omsk State University,Omsk,Russian Federation;3.Omsk State Technical University,Omsk,Russian Federation;4.Omsk Scientific Center,Siberian Branch of the Russian Academy of Sciences,Omsk,Russian Federation |
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| Abstract: | The bimetallic PdRu catalyst supported on carbon nanotubes were found ot provide an efficient synthesis of cyclopentanol in aqueous-phase hydrogenation of furfural. Under the chosen reaction conditions (temperature of 473 K, total pressure of 8 MPa), the selectivity towards cyclopentanol reaches 77% at a complete conversion of furfural. A high activity of this catalyst can be associated with changes in the electronic state and dispersion of the supported metals caused by their mutual interaction and formation of PdRu alloy. |
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