Synthesis,characterization and biological activity studies of octahedral nickel(II) complexes |
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Authors: | Ram N Patel Anurag Singh Krishna K Shukla Dinesh K Patel Vishnu P Sondhiya |
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Institution: | (1) Department of Chemistry, A. P. S. University, Rewa, 486003, Madhya Pradesh, India |
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Abstract: | Abstract Three nickel(II) complexes, namely Ni(BH)3](H2O)(NO3)(ClO4) 1, Ni(BH)2(NO3)2] 2 and Ni(BH)(Tren)](ClO4)2
3 (BH = Benzoylhydrazine, Tren = Tris(2-aminoethyl)amine) have been synthesized and characterized by physico-chemical techniques.
X-ray crystallographic analysis shows the nickel to be six-coordinated in these complexes. The complexes are efficient catalysts
for the dismutation of superoxide in alkaline DMSO-NBT assays. The IC50 values are 74,108 and 105 μM for 1, 2 and 3, respectively. |
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