| 微波固相合成苯并[a]吩噁嗪衍生物 |
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| 引用本文： | 龙江,金津,王永梅,孟继本.微波固相合成苯并[a]吩噁嗪衍生物[J].高等学校化学学报,1999,20(4):573. |
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| 作者姓名： | 龙江 金津 王永梅 孟继本 |
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| 作者单位： | 南开大学化学系, 天津 300071 |
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| 基金项目： | 国家自然科学基金,国家教育部博士点基金 |
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| 摘 要： | 首次在固相条件下微波辐射N,N-二烷基-4-亚硝基苯胺盐酸盐和2-萘酚衍生物快速合成苯并a]吩嗪衍生物,得到苯并a]吩嗪离子氯化物3a-3f,且收率较高.此外,N,N-二甲基-4-亚硝基苯胺盐酸盐和1,3-二羟基-2-萘甲酸乙酯的混合物在微波辐射下合成了一个新的激光染料9-二甲氨基-6-乙氧羰基-5H-苯并a]的吩 嗪-5-酮4.
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| 关 键 词： | 微波辐射 固相合成 苯并[a]吩嗪离子氯化物 激光染料 5H－苯并[a]吩嗪－5－酮 |
| 收稿时间： | 1998-08-24 |
Microwave Irradiated Synthesis of Benzo phenoxazine Derivatives in Solid State |
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| LONG Jiang,JIN Jin,WANG YongMei,MENG JiBen.Microwave Irradiated Synthesis of Benzo phenoxazine Derivatives in Solid State[J].Chemical Research In Chinese Universities,1999,20(4):573. |
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| Authors: | LONG Jiang JIN Jin WANG YongMei MENG JiBen |
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| Institution: | Department of Chemistry, Nankai University, Tianjin, 300071 |
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| Abstract: | A new methodology quickly leading to benzo phenoxazine derivatives is reported. The mixture of N,Ndialkyl4nitrosoaniline hydrochloride and 2naphthol derivatives was irradiated in domestic microwave oven in the absence of solvent to afford benzoa]phenoxazonium chlorides 3a_3f with a high yield and the results were compared with the conditions reacted in supporters, oilbath or solvent. Moreover, a new laser dye 9dimethylamino6carbethoxy5Hbenzo phenoxazin5one was prepared. |
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| Keywords: | Microwave irradiation Solid state synthesis Benzo phenoxazonium chloride Laser dyes 5HBenzo phenoxazin5one |
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