Synthesis of nonactin and the proposed structure of trilactone |
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| Authors: | Wu Yikang Sun Ya-Ping |
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| Affiliation: | State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, China. yikangwu@mail.sioc.ac.cn |
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| Abstract: | [reaction: see text] An efficient enantioselective route to nonactin using a novel beta-inversion of an Evans syn aldol to construct the THF ring is presented. Through total synthesis, the structure for trilactone proposed in the literature is shown likely to be incorrect. |
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