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| Unprecedented Pseudo Water Tapes Stabilized by a One-dimensional Cu（Ⅱ） Coordination Polymer | |
| 引用本文： | 杨娥,陈顺玉,刘子生,李俊篯.Unprecedented Pseudo Water Tapes Stabilized by a One-dimensional Cu（Ⅱ） Coordination Polymer[J].结构化学,2011,30(1):101-104. |
| 作者姓名： | 杨娥 陈顺玉 刘子生 李俊篯 |
| 作者单位： | Department of Chemistry;Fuzhou University;College of Chemistry & Materials Science;Fujian Normal University;Fujian Institute of Research on the Structure of Matter;Chinese Academy of Sciences; |
| 基金项目： | supported by the Natural Science Foundation of Fujian Province (No.2010J01029) |
| 摘 要： | A new compound,Cu(mal)(tmdpy)(H2O)]·4H2O(1,H2mal = malonic acid,tmdpy = 4,4'-trimethylenedipyridine) has been synthesized by the hydrothermal synthesis and structurally characterized by X-ray crystallography. It crystallizes in triclinic,space group P1 with a = 9.1662(6),b = 10.6266(7),c = 11.3056(7) ,α = 84.6390(10),β = 72.1030(10),γ = 73.0420(10) o,V = 1002.37(11) 3,C16H26CuN2O9,Mr = 453.93,Z = 2,Dc = 1.504 g/cm3,μ = 1.140 mm-1,F(000) = 474,R = 0.0375 and wR = 0.0975 for 3187 observed reflections(I > 2σ(I)) . In the structure of 1,the tmdpy ligands link the Cu(mal)(H2O) ] units into an infinite chain,and the water molecules and carboxylate oxygen donors(O(2) and O(4)) from the mal ligands cooperatively built an interesting hydrogen bonding network with unprecedented pseudo water tape substructures. |
| 关 键 词： | 配位聚合物 水带 铜 一维 稳定 水热合成 结构特征 三斜晶系 |
Unprecedented Pseudo Water Tapes Stabilized by a One-dimensional Cu(Ⅱ)Coordination Polymer |
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| YANG E,CHEN Shun-Yu,LIU Zi-Sheng,LI Jun-Qian.Unprecedented Pseudo Water Tapes Stabilized by a One-dimensional Cu(Ⅱ)Coordination Polymer[J].Chinese Journal of Structural Chemistry,2011,30(1):101-104. | |
| Authors: | YANG E CHEN Shun-Yu LIU Zi-Sheng LI Jun-Qian |
| Institution: | 1. Department of Chemistry, Fuzhou University, Fuzhou 350002, China;College of Chemistry & Materials Science, Fujian Normal University, Fuzhou 350007, China 2. College of Chemistry & Materials Science, Fujian Normal University, Fuzhou 350007, China 3. Department of Chemistry, Fuzhou University, Fuzhou 350002, China;Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China |
| Abstract: | A new compound,Cu(mal)(tmdpy)(H2O)]·4H2O(1,Hemal = malonic acid,tmdpy= 4,4'-trimethylenedipyridine)has been synthesized by the hydrothermal synthesis and structurally characterized by X-ray crystallography.It crystallizes in triclinie,space group P1 with a =9.1662(6),b=10.6266(7),c=11.3056(7)(A), α=84.6390(10),β=72.1030(10),y=73.0420(10)°,V=1002.37(11)(A)3,C16H26CuN2O9,Mr=453.93,Z=2,Dc=1.504 g/cm3,μ=1.140 mm-1,F(000)=474,R=0.0375 and wR=0.0975 for 3187 observed reflections(I＞2σ(I)).In the structure of 1,the tmdpy ligands link theCu(mal)(H2O)]units into an infinite chain,and the water molecules and earboxylate oxygen donors(O(2)and O(4))from the mal ligands cooperatively built an interesting hydrogen bonding network with unprecedented pseudo water tape substructures. |
| Keywords: | hydrothermal synthesis crystal structure water cluster coordination polymer |
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