首页 | 本学科首页   官方微博 | 高级检索  
     检索      


A novel copper cobalt inorganometallic cluster. Synthesis,structure and bonding analysis of Cu(3)[mu(2)-(CCHCo(2)(CO)(6))](3)
Authors:Vega Andrés  Calvo Víctor  Spodine Evgenia  Zárate Antonio  Fuenzalida Víctor  Saillard Jean-Yves
Institution:Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Casilla 233, Santiago, Chile.
Abstract:The reaction of the organometallic carboxylic acid HOOCCCHCo(2)(CO)(6) with copper(II) methoxide leads to a new inorganometallic cluster; Cu(3)mu(2)-(CCHCo(2)(CO)(6))](3). This cluster has a triangular core of copper(I) centers surrounded by three CCHCo(2)(CO)(6) fragments. The structure of the cluster has short Cu-Cu and Cu-Co distances (average 2.500 and 2.540 A, respectively). DFT calculations provide a rationalization of the peculiar bonding in this cluster.
Keywords:
本文献已被 PubMed 等数据库收录!
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号