Synthesis of palau’amide and its diastereomers: confirmation of its stereostructure |
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| Authors: | Hirokazu Sugiyama Kiyotake Suenaga |
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| Affiliation: | Department of Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku, Yokohama 223-8522, Japan |
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| Abstract: | Four diastereomers of palau’amide (1-4), a cytotoxic cyclodepsipeptide, were synthesized. The 1H NMR spectrum of 1 was identical to that of natural palau’amide. This established the complete stereostructure of palau’amide. |
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