Synthesis of ent-gabosine E from d-mannose by intramolecular nitrone-olefin cycloaddition |
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Authors: | Christos I Stathakis |
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Institution: | Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki GR 541 24, Greece |
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Abstract: | Intramolecular nitrone-olefin cycloaddition in a mannose template followed by N-O cleavage, quaternization of the resulting amine, and finally oxidative elimination of the amino group affords, after deprotection, ent-gabosine E in enantiomerically pure form. |
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