Oxidative Mannich reaction of N-carbobenzyloxy amines with 1,3-dicarbonyl compounds |
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| Authors: | Matsuo Jun-ichi Tanaki Yumi Ishibashi Hiroyuki |
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| Institution: | Division of Pharmaceutical Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. jimatsuo@p.kanazawa-u.ac.jp |
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| Abstract: | Efficient carbon-carbon bond formation at the alpha-position of nitrogen was established by one-pot oxidative Mannich reaction of N-carbobenzyloxy (Cbz) amines with 1,3-dicarbonyl compounds using N-tert-butylbenzenesulfinimidoyl chloride as an oxidant. |
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