A stereoselective cyclization to carbafuranose derivatives starting from 1,4-bis-epoxides |
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| Authors: | Leung Leo M H Boydell A James Gibson Vicky Light Mark E Linclau Bruno |
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| Affiliation: | School of Chemistry, University of Southampton, Highfield, Southampton SO17 1BJ, United Kingdom. |
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| Abstract: | [reactions: see text] A concise synthesis of highly functionalized cyclopentane derivatives via a Brook rearrangement mediated stereoselective linchpin cyclization reaction involving tert-butyldimethylsilyl-1,3-dithianyllithium and homochiral 1,4-bis-epoxides is described. |
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