| Abstract: | By reaction between bis(dichlorophosphoryl)imide and hexamethyldisilazane – with or without solvent – the authors obtain two phases. The solid phase is the ammonium salt of the bis(dichlorophosphoryl)imide which can be obtained, like many other metallic salts of this type, by the general reaction:  . The salt is characterized by its I.R., and 31P, 1H, and 14N N.M.R. spectra and by its hydrolysis reaction. The composition of the liquid phase changes according the experimental conditions. It seems that at first the main components are Cl2(O)P? N?P(OSiMe3)Cl2 and Cl2(Me3SiO)P?N? PCl(OH)NSiMe3. These compounds condense further to high polymers. |
